Реферат: The thermal decomposition of azidoacetone, ethyl azidoacetate, benzyl azide, p-nitrobenzyl azide, cyclohexyl azide, and phenyl azide proceeds with initial rupture of the N-N bond in the azido-group. The rate of decomposition of azido-compounds depends on the type of substituent present in the position alpha - to the azido-group. Bearing in mind the low values of the energy of activation (158-165 kJ/mole), it may be assumed that the decomposition of azido-compounds, like that of nitro-compounds, involves a semirigid activated complex in which rocking vibrations of the original molecule are not transformed into free rotation, but only decrease their frequency.

Библиографическая ссылка: Stepanov R.S. , Kruglyakova L.A. , Buka E.S.
Kinetics of the thermal decomposition of substituted alkyl and aryl azides
Kinetics and Catalysis. 1986. V.27. N2. P.414-416. WOS Scopus

Оригинальная версия: Степанов Р.С. , Круглякова Л.А. , Бука Э.С.
Кинетика термического разложения замещенных алкил- и арилазидов
Кинетика и катализ. 1986. Т.27. №2. С.479-482. CAPlusCAРЖ ВИНИТИ

Даты:

Поступила в редакцию:	3 дек. 1984 г.
Опубликована в печати:	1 мар. 1986 г.

Идентификаторы БД:

Web of science:	WOS:A1986F054100017
Scopus:	2-s2.0-0022678899

Цитирование в БД:

БД	Цитирований
Web of science	7