Реферат: The macrokinetics of reactions of aliphatic carboxylic acid chlorides with sodium azide in an acetonitrile medium was studied. It was found that these reactions are typical of chemical dissolution processes with the formation of a solid reaction product on the surface of the dissolving sodium azide crystal. It was shown that at low temperatures, the process rate is limited by the rate of dissolution of sodium azide, and at high temperatures by the internal diffusion of the acid chloride in the particle pores, slowing down as the result of the counterflow of nitrogen, evolving during the decomposition of acyl azide. An equation was established for the dependence at low temperatures of the specific rate of the reaction on the temperature and concentration of the acid chloride.

Библиографическая ссылка: Zlobin V.A. , Tarasov A.K.
Macrokinetics of reaction of sodium azide with aliphatic carboxylic acid chlorides in acetonitrile
Kinetics and Catalysis. 1986. V.27. N6. P.1277-1280. WOS Scopus

Оригинальная версия: Злобин В.А. , Тарасов А.К.
Макрокинетика реакции азида натрия с хлорангидридами алифатических карбоновых кислот в ацетонитриле
Кинетика и катализ. 1986. Т.27. №6. С.1468-1471. CAPlusCAРЖ ВИНИТИ

Даты:

Поступила в редакцию:	9 сент. 1985 г.
Опубликована в печати:	1 нояб. 1986 г.

Идентификаторы БД:

Web of science:	WOS:A1986J284600015
Scopus:	2-s2.0-0022813780