The Kinetics of Thermal Decomposition of Acetyl-cyclo-hexylsulfonylperoxide | Sciact

The Kinetics of Thermal Decomposition of Acetyl-cyclo-hexylsulfonylperoxide Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2002, Том: 43, Номер: 3, Страницы: 312-315 Страниц : 4 DOI: 10.1023/A:1016097532393

Авторы

Zaripov R.N. , Murzagulova E.I. , Garifullina G.F. , Safiullin R.L. , Komissarov V.D.

Организации

1	Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, 450054, Russia

The kinetics of the decomposition of acetyl-cyclo-hexylsulfonylperoxide (SP, RS(O-2)OOC(O)CH3, R = cyclo-C6H11) was studied in a C6H4Cl2 Solution in an O-2 atmosphere at 323-353 K and in an Ar atmosphere at 323-343 K. The rate constants of SP monomolecular decomposition (k(1)) and SP reaction with CH3. radicals (k(3)) were determined. The temperature dependences of these rate constants are described by equations logk(1) = (14.5 +/- 2.9) - (115.4 +/- 19.0) - (2.3RT) and logk(3) = (11.6 +/- 2.2) - (44.6 +/- 14.2)/(2.3RT), where the activation energies are expressed in kJ/mol.

Zaripov R.N. , Murzagulova E.I. , Garifullina G.F. , Safiullin R.L. , Komissarov V.D.
The Kinetics of Thermal Decomposition of Acetyl-cyclo-hexylsulfonylperoxide
Kinetics and Catalysis. 2002. V.43. N3. P.312-315. DOI: 10.1023/A:1016097532393 WOS Scopus РИНЦ CAPlus OpenAlex

Зарипов Р.Н. , Мурзагулова Э.И. , Гарифуллина Г.Ф. , Сафиуллин Р.Л. , Комиссаров В.Д.
Кинетика термического разложения ацетилциклогексилсульфонилпероксида
Кинетика и катализ. 2002. Т.43. №3. С.342-345. РЖ ВИНИТИ

Поступила в редакцию:	23 окт. 2000 г.
Опубликована в печати:	1 мая 2002 г.

Web of science:	WOS:000176749200003
Scopus:	2-s2.0-0038078720
РИНЦ:	13407361
Chemical Abstracts:	2002:484278
OpenAlex:	W149138717