Catalytic Conversions of Lower Alkanethiols to Dialkyl Sulfides Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 1997, Volume: 38, Number: 4, Pages: 541-547 Pages count : 7 | ||
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Abstract:
The possibility of the selective conversion of lower alkanethiols RSH (R = C-1-C-3) to dialkyl sulfides in the presence of the modified alumina catalyst was demonstrated. The corresponding symmetrical dialkyl sulfides were produced as a result of the alkanethiol disproportionation, and the methylalkyl sulfides were produced by reactions of alkanethiols with methanol. The rate of the alkane methanethiol conversion changed in the following order: iso-C3H7SH > C2H5SH > CH3SH. Methanethiol quantitatively converted to dimethyl sulfide; ethanethiol and especially propanethiol-2 reacted less selectively because of the decomposition reaction. The process is inhibited in the case of a mixture of alkanethiols.
Cite:
Mashkina A.V.
, Yakovleva V.N.
Catalytic Conversions of Lower Alkanethiols to Dialkyl Sulfides
Kinetics and Catalysis. 1997. V.38. N4. P.541-547. WOS Scopus РИНЦ ANCAN
Catalytic Conversions of Lower Alkanethiols to Dialkyl Sulfides
Kinetics and Catalysis. 1997. V.38. N4. P.541-547. WOS Scopus РИНЦ ANCAN
Original:
Машкина А.В.
, Яковлева В.Н.
Каталитические превращения низших алкантиолов в диалкилсульфиды
Кинетика и катализ. 1997. Т.38. №4. С.591-597. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Каталитические превращения низших алкантиолов в диалкилсульфиды
Кинетика и катализ. 1997. Т.38. №4. С.591-597. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Dates:
| Submitted: | Feb 1, 1996 |
| Published print: | Jul 1, 1997 |
Identifiers:
| Web of science: | WOS:A1997XU99700016 |
| Scopus: | 2-s2.0-0642366469 |
| Elibrary: | 13266553 |
| Chemical Abstracts: | 1997:597180 |
| Chemical Abstracts (print): | 127:277855 |