Elementary Steps of the Gas-Phase Catalytic Oxidation of CO in the Presence of Rhenium Cations with Carbonyl and Oxygen Ligands: A Comparison with Heterogeneous Catalysis Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 1997, Volume: 38, Number: 5, Pages: 589-594 Pages count : 6 | ||
| Tags | BOND-DISSOCIATION ENERGIES; TRANSITION-METAL IONS | ||
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Abstract:
The reactivity of rhenium (Re+) and rhenium monocarbonyl (ReCO+) cations in the gas phase toward CO oxidation by oxygen-containing reagents (NO, O-2, and N2O) was studied by ion cyclotron resonance. The presence of a carbonyl ligand significantly affects the ion reactivity. An effective route of metal monocarbonyl ion oxidation by molecular oxygen was found. This step can explain low-temperature activity of a number of oxide catalysts in the reaction of CO oxidation by molecular oxygen.
Cite:
Goncharov V.B.
, Fialko E.F.
, Sheinin D.E.
, Kikhtenko A.V.
Elementary Steps of the Gas-Phase Catalytic Oxidation of CO in the Presence of Rhenium Cations with Carbonyl and Oxygen Ligands: A Comparison with Heterogeneous Catalysis
Kinetics and Catalysis. 1997. V.38. N5. P.589-594. WOS Scopus РИНЦ ANCAN
Elementary Steps of the Gas-Phase Catalytic Oxidation of CO in the Presence of Rhenium Cations with Carbonyl and Oxygen Ligands: A Comparison with Heterogeneous Catalysis
Kinetics and Catalysis. 1997. V.38. N5. P.589-594. WOS Scopus РИНЦ ANCAN
Original:
Гончаров В.Б.
, Фиалко Е.Ф.
, Шейнин Д.Э.
, Кихтенко А.В.
Исследование элементарных стадий каталитического окисления CO в газовой фазе в присутствии катионов рения с карбонильными и кислородными лигандами. Сравнение с гетерогенным катализом
Кинетика и катализ. 1997. Т.38. №5. С.645-650. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Исследование элементарных стадий каталитического окисления CO в газовой фазе в присутствии катионов рения с карбонильными и кислородными лигандами. Сравнение с гетерогенным катализом
Кинетика и катализ. 1997. Т.38. №5. С.645-650. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Dates:
| Submitted: | Aug 19, 1996 |
| Published print: | Sep 1, 1997 |
Identifiers:
| Web of science: | WOS:A1997YD16800001 |
| Scopus: | 2-s2.0-0642301368 |
| Elibrary: | 13263135 |
| Chemical Abstracts: | 1997:705182 |
| Chemical Abstracts (print): | 128:13017 |