Structure of Mo(VI), V(V), and Ti(IV) Alkylperoxy and Peroxy Complexes Deduced from NMR Data and Their Reactivity

Structure of Mo(VI), V(V), and Ti(IV) Alkylperoxy and Peroxy Complexes Deduced from NMR Data and Their Reactivity Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1997, Volume: 38, Number: 5, Pages: 619-629 Pages count : 11

Tags

HYDROGEN-PEROXIDE; ORGANIC HYDROPEROXIDES; AROMATIC-HYDROCARBONS; COBALT(III) ACETATE; COBALTIC ACETATES; EPOXIDATION; OLEFINS; AUTOXIDATION; ALKANES; O-17

Authors

Talsi E.P. , Shalyaev K.V. , Babushkin D.E. , Sobolev A.P. , Zamaraev K.I.

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

NMR-spectroscopic studies of V-51, (MO)-M-95, Co-59, O-17, and H-1 nuclei present in coordination compounds that catalyze alkene and alkane oxidation with organic hydroperoxides are reviewed. Multinuclear NMR spectroscopy was shown to have advantages in structural studies of selective oxidation intermediates.

Talsi E.P. , Shalyaev K.V. , Babushkin D.E. , Sobolev A.P. , Zamaraev K.I.
Structure of Mo(VI), V(V), and Ti(IV) Alkylperoxy and Peroxy Complexes Deduced from NMR Data and Their Reactivity
Kinetics and Catalysis. 1997. V.38. N5. P.619-629. WOS Scopus РИНЦ ANCAN

Талзи Е.П. , Шаляев К.В. , Бабушкин Д.Э. , Соболев А.П. , Замараев К.И.
Строение по данным ЯМР и реакционная способность алкилпероксо- и пероксокомплексов Mo(VI), V(V) и Ti(IV)
Кинетика и катализ. 1997. Т.38. №5. С.678-689. РИНЦ publication_identifier_short.rz_viniti_identifier_type

Submitted:	Oct 20, 1995
Published print:	Sep 1, 1997

Web of science:	WOS:A1997YD16800006
Scopus:	2-s2.0-0642270660
Elibrary:	13259870
Chemical Abstracts:	1997:705187
Chemical Abstracts (print):	128:12973

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