Abstract: Electrochemical methane conversion in a cell with the solid oxygen-conducting electrolyte (CH4, Pt\0.9ZrO(2) + O.1Y(2)O(3)\Pt + PrO2, air) was studied. The platinum electrode was found to be an active electrode/catalyst for partial methane oxidation to syngas with the ratio [H-2]/[CO] approximate to 2. At 800 degrees C, the selectivity to carbon monoxide formation and its yield reach 80 and 65%, respectively. At 660-700 degrees C, electrochemically generated oxygen oxidizes methane to syngas more efficiently than oxygen adsorbed from the gas phase. New possibilities and advantages of the electrochemical route of methane oxidation to syngas were compared to the same process in a normal kinetics mode.

Cite: Galʹvita V.V. , Belyaev V.D. , Sobyanin V.A.
Electrochemical Methane Oxidation to Syngas on the Pt Electrode in a Cell with the Solid Oxygen-Conducting Electrolyte
Kinetics and Catalysis. 1997. V.38. N5. P.673-677. WOS Scopus РИНЦ ANCAN

Original: Гальвита В.В. , Беляев В.Д. , Собянин В.А.
Электрохимическое окисление метана до синтез-газа на Pt-электроде в ячейке с твердым кислородпроводящим электролитом
Кинетика и катализ. 1997. Т.38. №5. С.736-741. РИНЦ publication_identifier_short.rz_viniti_identifier_type publication_identifier_short.sciact_identifier_type

Dates:

Submitted:	Apr 24, 1996
Published print:	Sep 1, 1997

Identifiers:

Web of science:	WOS:A1997YD16800014
Scopus:	2-s2.0-0642332053
Elibrary:	13261549
Chemical Abstracts:	1997:705195
Chemical Abstracts (print):	128:54569

Citing:

DB	Citing
Web of science	2