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Catalytic Properties of Alkali-promoted Vanadium Catalysts for Oxidation of Sulfur Dioxide Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1997, Volume: 38, Number: 6, Pages: 820-824 Pages count : 5
Tags SO2 OXIDATION; MELTS; DEACTIVATION; V2O5-CS2S2O7; SYSTEMS
Authors Simonova L.G. , Bulgakova Y.O. , Lapina O.B. , Balʹzhinimaev B.S.
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Abstract: Alkali-promoted catalysts M-2' S2O7-M-2 " S2O-rV(2)O(5)/SiO2 (M' = Cs, Rb, and K; M " = K, Na, and Li) of various compositions for synthesis of sulfuric acid were studied in the range of low temperatures and conversions. Light alkali metals M " were shown to be able to increase or decrease the catalytic activity depending on the nature of the main promoter M'. In the context of molecular concepts of the structure of vanadium catalysts and the mechanism of their catalytic activity, plausible reasons for the positive and negative influence of alkali promoters on the rate of oxidation of SO2 to SO3 were discussed
Cite: Simonova L.G. , Bulgakova Y.O. , Lapina O.B. , Balʹzhinimaev B.S.
Catalytic Properties of Alkali-promoted Vanadium Catalysts for Oxidation of Sulfur Dioxide
Kinetics and Catalysis. 1997. V.38. N6. P.820-824. WOS Scopus РИНЦ ANCAN
Original: Симонова Л.Г. , Булгакова Ю.О. , Лапина О.Б. , Бальжинимаев Б.С.
Каталитические свойства ванадиевых катализаторов окисления диоксида серы, промотированных щелочными металлами
Кинетика и катализ. 1997. Т.38. №6. С.891-895. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Dates:
Submitted: Jul 16, 1996
Published print: Nov 1, 1997
Identifiers:
Web of science: WOS:000071180900016
Scopus: 2-s2.0-0347823975
Elibrary: 13261537
Chemical Abstracts: 1998:18753
Chemical Abstracts (print): 128:53698
Citing:
DB Citing
Web of science 1
Scopus 1