Abstract: The relative yield of heavy hydrocarbons in the title reaction can be increased by increasing the surface Co concentration in the catalyst and by preliminary treatment of the catalyst with O2. Transition metal oxide supports lead to the highest yields of heavy hydrocarbons. A low Co content leads to a decreased CH4 content in the light products and to an increased yield of olefins. The activity of the catalyst decreased in the following order of supports: SiO2 ∼ TiO2 > ZrO2 ≥ γ-​Al2O3 > MgO.

Cite: Lisitsyn A.S. , Kuznetsov V.L. , Ermakov Y.I.
Catalysts Obtained by the Reaction of Transition Element Organometallic Compounds with Oxide Support Surfaces. Catalytic Properties of Systems Prepared by the Pyrolysis of Co2(CO)8 on Oxide Supports in the Reaction CO+H2 Depending on Their Composition and Pretreatment
Kinetics and Catalysis. 1982. V.23. N4. P.783-787. WOS РИНЦ

Original: Лисицын А.С. , Кузнецов В.Л. , Ермаков Ю.И.
Катализаторы, полученные взаимодействием металлоорганических соединений переходных элементов с поверхностью окисных носителей. Каталитические свойства систем, приготовленных пиролизом Co2(CO)8 на окисных носителях, в реакции CO+H2 в зависимости от их состава и предварительной обработки
Кинетика и катализ. 1982. Т.23. №4. С.926-931. РИНЦ ANCANpublication_identifier_short.rz_viniti_identifier_type publication_identifier_short.sciact_identifier_type

Dates:

Submitted:	Jul 1, 1981
Published print:	Jul 1, 1982

Identifiers:

Web of science:	WOS:A1982QJ96100006
Elibrary:	30640730

Citing:

DB	Citing
Web of science	2