Реферат: It was found that in the reaction of H2S with the oxidized surface of Sn-Mo oxide catalyst at 293 K, it dissociates at both S-H bonds with the participation of a Mo-containing surface compound and exchange of O2- ions for S2- ions, resulting in reduction of this compound with the formation of MoS2 and liberation of water. Some of the S2- ions are simultaneously oxidized into sulfate-like structures at room temperature. It was shown that the sulfidized form of the Mo-containing compound is easily reoxidized by reverse exchange between S2- and O2-. Water slows the exchange reaction between O2- and S2-.

Библиографическая ссылка: Kasumov F.B. , Davydov A.A. , Kerimov I.Y.
The Claus Reaction. 1. IR Spectroscopic Study of the Reaction of H2S with the Surface of an Sn-Mo Oxide Catalyst
Kinetics and Catalysis. 1992. V.32. N5 pt 2. P.1067-1072. WOS РИНЦ

Оригинальная: Касумов Ф.Б. , Давыдов А.А. , Керимов И.Я.
Реакция Клауса. I. Изучение взаимодействия H2S с поверхностью Sn-Mo оксидного катализатора методом ИК-спектроскопии
Кинетика и катализ. 1991. Т.32. №5. С.1187-1192. РИНЦ CAPlusCAРЖ ВИНИТИ

Даты:

Поступила в редакцию:	19 апр. 1990 г.
Опубликована в печати:	1 апр. 1992 г.

Идентификаторы БД:

Web of science:	WOS:A1991HV78000007
РИНЦ:	21753874

Цитирование в БД: Пока нет цитирований