Kinetics and mechanism of the carbonylation of methanol to methyl formate | Sciact

Kinetics and mechanism of the carbonylation of methanol to methyl formate Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1986, Том: 27, Номер: 5, Страницы: 968-973 Страниц : 6

Авторы

Tagaev O.A. , Pazderskii Yu.A. , Gutor I.M. , Moiseev I.I.

Организации

1	Kurnakov Institute of General and Inorganic Chemistry RAS

The rate of carbonylation of methanol to methyl formate in methanol solutions of sodium methylate within the range 1-4 MPa and 80-110° obey the first-order equation with respect to the concentrations of sodium methylate, carbon monoxide, and methanol (k = 10(7,84±0,23) exp (-15 000±400)/RT, liters2/mole2∙min). Under the same conditions the rate of decarbonylation of methyl formate is proportional to the concentrations of sodium methylate and methyl formate to the first power (k = 10(13,43±0,37) exp (-24 200±600)/RT, liter/mole∙min).

Tagaev O.A. , Pazderskii Y.A. , Gutor I.M. , Moiseev I.I.
Kinetics and mechanism of the carbonylation of methanol to methyl formate
Kinetics and Catalysis. 1986. V.27. N5. P.968-973. WOS Scopus

Тагаев О.А. , Паздерский Ю.А. , Гутор И.М. , Моисеев И.И.
Кинетика и механизм карбонилирования метанола в метилформиат
Кинетика и катализ. 1986. Т.27. №5. С.1122-1127. CAPlusCAРЖ ВИНИТИ

Поступила в редакцию:	5 мая 1985 г.
Опубликована в печати:	1 сент. 1986 г.

Web of science:	WOS:A1986H751200013
Scopus:	2-s2.0-0022785063