A novel catalytic olefination reaction. Unusual transformation of a copper-carbene complex - Доклады на конференциях

A novel catalytic olefination reaction. Unusual transformation of a copper-carbene complex Доклады на конференциях

Язык

Английский

Тип доклада

Стендовый

Конференция

VI Russian Conference on Catalytic Reaction Mechanisms
01-05 окт. 2002 , Москва

Авторы

Ненайденко В Г ¹ , Коротченко В Н ¹ , Шастин А В ² , Баленкова Е С ¹

Организации

1	Московский государственный университет им. М.В. Ломоносова
2	Федеральный исследовательский центр проблем химической физики и медицинской химии РАН

PP-131 Новая каталитическая реакция олефинирования. Необычное превращение медь-карбенового комплекса A novel catalytic approach to olefination of carbonyl compounds is proposed. A wide range of substituted alkenes can be obtained in high yields. Mild conditions and simplicity of the technique are significant features of the presented method. Possible mechanism of the new olefination reaction is discussed. It was found that the key intermediate· - a copper-carbene complex - showed the unusual behavior under reaction conditions.

Nenaidenko V.G. , Korotchenko V.N. , Shastin A.V. , Balenkova E.S.
A novel catalytic olefination reaction. Unusual transformation of a copper-carbene complex
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002