Реферат: PP-167 Катализ водно-щелочного окисления этиленгликоля палладированным сибунитом Kinetics of aqueous alkali ethylene glycol oxidation on sibunit supported palladium catalyst was investigated. Kinetic model incorporating description of the substrate oxidation in terms of Langmuir-Hinshelwood kinetics and description of reversible over-oxidation of metal catalyst surface in terms of subsurface oxygen formation is proposed. Important role of alkali for over-oxidized catalyst reactivation is indicated.

Библиографическая ссылка: Staroverov D.V. , Varlamova E.V. , Shvets V.F.
Catalysis of the aqueous alkali ethylene glycol oxidation by sibunit supported palladium
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002