Kinetics and mechanism of photocatalytic reduction of nitric oxides by carbon monoxide - Доклады на конференциях

Kinetics and mechanism of photocatalytic reduction of nitric oxides by carbon monoxide Доклады на конференциях

Язык

Английский

Тип доклада

Устный

Конференция

VI Russian Conference on Catalytic Reaction Mechanisms
01-05 окт. 2002 , Москва

Авторы

Шелимов Б Н ¹ , Субботина Ирина Рудольфовна ¹ , Che M ² , Coluccia S ³

Организации

1	Институт органической химии им. Н. Д. Зелинского РАН
2	Universite Pierre et Marie Curie
3	University of Turin

OP-I-12 Кинетика и механизм фотокаталитического восстановления оксидов азота монооксидом углерода In order to contribute to the problem of environmental protection, selective catalytic reduction of NO and N2O by carbon monoxide to nontoxic products under UV-irradiation has been investigated using silica-supported molybdenum oxide (MoOJ/SiO2) as a photocatalyst. At 20°C, photocatalytic reduction of NO by carbon monoxide readily occurs, N2, N2O and CO2 being the reaction products. The N2/N2O ratio depends on the irradiation time. The photoreaction is a true photocatalytic process (TON>> 1). Секция: Секция I: Reductive-oxidative heterogeneous catalysis

Shelimov B.N. , Subbotina I.R. , Che M. , Coluccia S.
Kinetics and mechanism of photocatalytic reduction of nitric oxides by carbon monoxide
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002