Реферат: OP-II-14 Активация пероксида водорода, дибензилового эфира и его гидропероксида полиядерными комплексами 3d-металлов The catalytic properties of 3d metals homo- and heterometalic polynuclear (up to 12 metal atoms in core) carboxylates in the H2O2 decomposition and dibenzyl ether (DBE) liquid-phase oxidation are reviewed. Special attention is paid to catalytic systems formation depending on a nature of reaction system and parent complex. In the presence of investigated complexes the factors of benzyl a-CH-bond activation both in DBE and the hydroperoxide (HP) are equal and the substrates activation proceeds on the same catalytic centre. HP catalytic decomposition in DBE oxidates noticeably differs in the presence and absence of oxygen and limiting stage of the process is the HP•Cat complex formation. Секция: Секция II: Acid-base heterogeneous and homogeneous catalysis

Библиографическая ссылка: Kamalov G.L. , Chikhichin D.G. , Levchenko O.A. , Kotseruba V.A.
Hydrogen peroxide, dibenzyl ether and its hydroperoxide activation by polynuclear complexes of 3d metals
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002