Catalytic Conversions of Lower Alkanethiols to Dialkyl Sulfides Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 1997, Том: 38, Номер: 4, Страницы: 541-547 Страниц : 7 | ||
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Реферат:
The possibility of the selective conversion of lower alkanethiols RSH (R = C-1-C-3) to dialkyl sulfides in the presence of the modified alumina catalyst was demonstrated. The corresponding symmetrical dialkyl sulfides were produced as a result of the alkanethiol disproportionation, and the methylalkyl sulfides were produced by reactions of alkanethiols with methanol. The rate of the alkane methanethiol conversion changed in the following order: iso-C3H7SH > C2H5SH > CH3SH. Methanethiol quantitatively converted to dimethyl sulfide; ethanethiol and especially propanethiol-2 reacted less selectively because of the decomposition reaction. The process is inhibited in the case of a mixture of alkanethiols.
Библиографическая ссылка:
Mashkina A.V.
, Yakovleva V.N.
Catalytic Conversions of Lower Alkanethiols to Dialkyl Sulfides
Kinetics and Catalysis. 1997. V.38. N4. P.541-547. WOS Scopus РИНЦ CAPlusCA
Catalytic Conversions of Lower Alkanethiols to Dialkyl Sulfides
Kinetics and Catalysis. 1997. V.38. N4. P.541-547. WOS Scopus РИНЦ CAPlusCA
Оригинальная:
Машкина А.В.
, Яковлева В.Н.
Каталитические превращения низших алкантиолов в диалкилсульфиды
Кинетика и катализ. 1997. Т.38. №4. С.591-597. РИНЦ РЖ ВИНИТИ
Каталитические превращения низших алкантиолов в диалкилсульфиды
Кинетика и катализ. 1997. Т.38. №4. С.591-597. РИНЦ РЖ ВИНИТИ
Даты:
| Поступила в редакцию: | 1 февр. 1996 г. |
| Опубликована в печати: | 1 июл. 1997 г. |
Идентификаторы БД:
| Web of science: | WOS:A1997XU99700016 |
| Scopus: | 2-s2.0-0642366469 |
| РИНЦ: | 13266553 |
| Chemical Abstracts: | 1997:597180 |
| Chemical Abstracts (print): | 127:277855 |