Реферат: Electrochemical methane conversion in a cell with the solid oxygen-conducting electrolyte (CH4, Pt\0.9ZrO(2) + O.1Y(2)O(3)\Pt + PrO2, air) was studied. The platinum electrode was found to be an active electrode/catalyst for partial methane oxidation to syngas with the ratio [H-2]/[CO] approximate to 2. At 800 degrees C, the selectivity to carbon monoxide formation and its yield reach 80 and 65%, respectively. At 660-700 degrees C, electrochemically generated oxygen oxidizes methane to syngas more efficiently than oxygen adsorbed from the gas phase. New possibilities and advantages of the electrochemical route of methane oxidation to syngas were compared to the same process in a normal kinetics mode.

Библиографическая ссылка: Galʹvita V.V. , Belyaev V.D. , Sobyanin V.A.
Electrochemical Methane Oxidation to Syngas on the Pt Electrode in a Cell with the Solid Oxygen-Conducting Electrolyte
Kinetics and Catalysis. 1997. V.38. N5. P.673-677. WOS Scopus РИНЦ CAPlusCA

Оригинальная: Гальвита В.В. , Беляев В.Д. , Собянин В.А.
Электрохимическое окисление метана до синтез-газа на Pt-электроде в ячейке с твердым кислородпроводящим электролитом
Кинетика и катализ. 1997. Т.38. №5. С.736-741. РИНЦ РЖ ВИНИТИ Sciact

Даты:

Поступила в редакцию:	24 апр. 1996 г.
Опубликована в печати:	1 сент. 1997 г.

Идентификаторы БД:

Web of science:	WOS:A1997YD16800014
Scopus:	2-s2.0-0642332053
РИНЦ:	13261549
Chemical Abstracts:	1997:705195
Chemical Abstracts (print):	128:54569

Цитирование в БД:

БД	Цитирований
Web of science	2