Ethylene Epoxidation over Silver Catalysts Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1999, Volume: 40, Number: 6, Pages: 795-810 Pages count : 16 | ||
Tags | SUPPORTED SILVER; CRYSTALLITE SIZE; PARTICLE-SIZE; Ag-109 NMR; ELECTRONIC-PROPERTIES; ETHENE EPOXIDATION; OXYGEN-ADSORPTION; PARTIAL OXIDATION; Ag(110)SURFACE | ||
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Abstract:
Physical and kinetic methods were used to study the structural, electron, and catalytic properties of silver catalysts for ethylene epoxidation: bulk silver (Ag(1 1 1) and foil), silver powder, and supported silver catalysts (Ag/α-Al2O3, Ag/SiO2, and Ag/C). The nature of size effects, the mechanism for the formation of active states of adsorbed oxygen, and the mechanism of ethylene epoxidation were determined. Based on these data, several unusual phenomena are explained and reasons for the unique catalytic activity of silver in ethylene epoxidation are discussed.
Cite:
Balʹzhinimaev B.S.
Ethylene Epoxidation over Silver Catalysts
Kinetics and Catalysis. 1999. V.40. N6. P.795-810. WOS Scopus РИНЦ ANCAN
Ethylene Epoxidation over Silver Catalysts
Kinetics and Catalysis. 1999. V.40. N6. P.795-810. WOS Scopus РИНЦ ANCAN
Original:
Бальжинимаев Б.С.
Эпоксидирование этилена на серебряных катализаторах
Кинетика и катализ. 1999. Т.40. №6. С.879-897. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Эпоксидирование этилена на серебряных катализаторах
Кинетика и катализ. 1999. Т.40. №6. С.879-897. РИНЦ publication_identifier_short.rz_viniti_identifier_type
Dates:
Submitted: | Apr 16, 1999 |
Published print: | Nov 1, 1999 |
Identifiers:
Web of science: | WOS:000084606000007 |
Scopus: | 2-s2.0-0042099448 |
Elibrary: | 13321449 |
Chemical Abstracts: | 2000:34069 |
Chemical Abstracts (print): | 132:182274 |