Abstract: The sequential oxidation of propylene at 573-​663 K on a catalyst composed of Bi, Co, Fe, and Ni molybdates, K, and P was studied. Formation of acrolein, acrylic acid, HOAc, CO, and CO2 was 1st order in the substrate being oxidized. The oxidation of propylene to acrolein was an autocatalytic process, accelerated by acrolein. H2O vapor increased acid formation, suppressed the complete oxidation of acrolein and HOAc, and did not affect acrylic acid oxidation. Rate constants and activation energies were detected for all steps.

Cite: Boreskov G.K. , Erenburg E.M. , Andrushkevich T.V. , Zelenkova T.V. , Bibin V.N. , Meshheryakov V.D. , Boronina N.P. , Tyurin Y.N.
Kinetics of Propylene Oxidation on Multicomponent Oxide Catalyst
Kinetics and Catalysis. 1982. V.23. N4. P.755-762. WOS РИНЦ

Original: Боресков Г.К. , Еренбург Е.М. , Андрушкевич Т.В. , Зеленкова Т.В. , Бибин В.Н. , Мещеряков В.Д. , Боронина Н.П. , Тюрин Ю.Н.
Кинетика окисления пропилена на окисном многокомпонентном катализаторе
Кинетика и катализ. 1982. Т.23. №4. С.895-902. РИНЦ ANCANpublication_identifier_short.rz_viniti_identifier_type

Dates:

Submitted:	Mar 23, 1981
Published print:	Jul 1, 1982

Identifiers:

Web of science:	WOS:A1982QJ96100001
Elibrary:	30640736

Citing:

DB	Citing
Web of science	4