Реферат: The effect of solvents of different donor capabilities on the rate and chemistry of the decomposition of dicyclohexyl peroxydicarbonate was studied at 0.1-500 MPa. Peroxide thermolysis takes place with initial formation of oxycarboxy radicals; these either react with solvents containing reactive C-H bonds, or are decarboxylated in inert medium. Increase in pressure increases the yield of cyclohexanol relative to cyclohexanone, and increases the amount of condensation. Formation of diphenylethane - by recombination of benzyl radicals - decreases with pressure and increase of initial peroxide concentration. When toluene-d8 is the solvent, with increase of initial peroxide concentration the roles of inductive decomposition and disproportionation increase relative to that of monomolecular decomposition.

Библиографическая ссылка: Antonovskii V.L. , Lipovich T.V.
Kinetics and chemistry of decomposition of dicyclohexyl peroxydicarbonate at high pressure
Kinetics and Catalysis. 1990. V.31. N6. P.1297-1301. WOS Scopus РИНЦ

Оригинальная версия: Антоновский В.Л. , Липович Т.В.
Кинетика и химизм распада дициклогексилпероксидикарбоната под высоким давлением
Кинетика и катализ. 1990. Т.31. №6. С.1479-1484. CAPlusCAРЖ ВИНИТИ

Даты:

Поступила в редакцию:	29 окт. 1987 г.
Принята к публикации:	28 июл. 1989 г.

Идентификаторы БД:

Web of science:	WOS:A1990FY99400013
Scopus:	2-s2.0-0026171505
РИНЦ:	31108662