Mechanism of carbonic acids formation on Vanadia-based oxide catalysts - Conference attendances

Mechanism of carbonic acids formation on Vanadia-based oxide catalysts Conference attendances

Language

Английский

Participant type

Стендовый

Conference

VI Russian Conference on Catalytic Reaction Mechanisms
01-05 Oct 2002 , Москва

Authors

Popova G.Ya. ¹ , Andrushkevich T.V. ¹ , Zakharov I.I. ¹ , Chesalov Yu.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

PP-146 Механизм образования карбоновых кислот на оксидных ванадийсодержаших катализаторах The vanadia-based oxide catalysts are active in the oxidation of formaldehyde, acrolein and P-picolin into formic, acrylic and nicotinic acids, accordingly. 1h situ IR investigation of surface intermediates transformations of CH2O and CH3C5H4N on V-Ti and C3H4O on V-Mo-oxide catalysts shows the mechanism similarity of aforenamed acids formation. The role of vanadium in formation of the acids is discussed.

Popova G.Y. , Andrushkevich T.V. , Zakharov I.I. , Chesalov Y.A.
Mechanism of carbonic acids formation on Vanadia-based oxide catalysts
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002