A novel catalytic olefination reaction. Unusual transformation of a copper-carbene complex - Conference attendances

A novel catalytic olefination reaction. Unusual transformation of a copper-carbene complex Conference attendances

Language

Английский

Participant type

Стендовый

Conference

VI Russian Conference on Catalytic Reaction Mechanisms
01-05 Oct 2002 , Москва

Authors

Nenaidenko V G ¹ , Korotchenko V N ¹ , Shastin A V ² , Balenkova E S ¹

Affiliations

1	Lomonosov Moscow State University
2	Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

PP-131 Новая каталитическая реакция олефинирования. Необычное превращение медь-карбенового комплекса A novel catalytic approach to olefination of carbonyl compounds is proposed. A wide range of substituted alkenes can be obtained in high yields. Mild conditions and simplicity of the technique are significant features of the presented method. Possible mechanism of the new olefination reaction is discussed. It was found that the key intermediate· - a copper-carbene complex - showed the unusual behavior under reaction conditions.

Nenaidenko V.G. , Korotchenko V.N. , Shastin A.V. , Balenkova E.S.
A novel catalytic olefination reaction. Unusual transformation of a copper-carbene complex
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002