Kinetics and mechanism of photocatalytic reduction of nitric oxides by carbon monoxide - Conference attendances

Kinetics and mechanism of photocatalytic reduction of nitric oxides by carbon monoxide Conference attendances

Language

Английский

Participant type

Устный

Conference

VI Russian Conference on Catalytic Reaction Mechanisms
01-05 Oct 2002 , Москва

Authors

Shelimov B N ¹ , Subbotina Irina Rudolʹfovna ¹ , Che M ² , Coluccia S ³

Affiliations

1	Zelinsky Institute of Organic Chemistry
2	Universite Pierre et Marie Curie
3	University of Turin

OP-I-12 Кинетика и механизм фотокаталитического восстановления оксидов азота монооксидом углерода In order to contribute to the problem of environmental protection, selective catalytic reduction of NO and N2O by carbon monoxide to nontoxic products under UV-irradiation has been investigated using silica-supported molybdenum oxide (MoOJ/SiO2) as a photocatalyst. At 20°C, photocatalytic reduction of NO by carbon monoxide readily occurs, N2, N2O and CO2 being the reaction products. The N2/N2O ratio depends on the irradiation time. The photoreaction is a true photocatalytic process (TON>> 1). Секция: Секция I: Reductive-oxidative heterogeneous catalysis

Shelimov B.N. , Subbotina I.R. , Che M. , Coluccia S.
Kinetics and mechanism of photocatalytic reduction of nitric oxides by carbon monoxide
VI Russian Conference on Catalytic Reaction Mechanisms 01-05 Oct 2002