Реферат: The possibility of alkyl radical generation on the heterogeneous catalysts far hydrocarbon pyrolysis is studied using radical freezing in the resonator of an ESR spectrometer. The pyrolysis of n-butane and n-undecane on the magnesium oxide samples with a defect structure is investigated. The higher the catalyst activity during pyrolysis, the higher its ability to generate additional ethyl radicals into the gas phase. The results provide the experimental evidence for the concept of the catalysis sphere based on the radical-chain theory of the heterogeneous-homogeneous reactions of the catalytic pyrolysis of hydrocarbons.

Библиографическая ссылка: Vasilʹeva N.A. , Ermolaev V.K. , Kuzʹmitskaya S.Y.
ESR Study of Radical Generation in the Course of Catalytic Pyrolysis of Hydrocarbons
Kinetics and Catalysis. 1999. V.40. N1. P.100-104. WOS Scopus РИНЦ CAPlusCA

Оригинальная: Васильева Н.А. , Ермолаев В.К. , Кузьмицкая С.Ю.
Исследование методом ЭПР генерации радикалов при каталитическом пиролизе углеводородов
Кинетика и катализ. 1999. Т.40. №1. С.111-115. РИНЦ РЖ ВИНИТИ

Даты:

Поступила в редакцию:	24 апр. 1996 г.
Опубликована в печати:	1 янв. 1999 г.

Идентификаторы БД:

Web of science:	WOS:000078894900015
Scopus:	2-s2.0-0042994065
РИНЦ:	13314278
Chemical Abstracts:	1999:176431
Chemical Abstracts (print):	130:281699

Цитирование в БД:

БД	Цитирований
Web of science	5