Abstract: The possibility of alkyl radical generation on the heterogeneous catalysts far hydrocarbon pyrolysis is studied using radical freezing in the resonator of an ESR spectrometer. The pyrolysis of n-butane and n-undecane on the magnesium oxide samples with a defect structure is investigated. The higher the catalyst activity during pyrolysis, the higher its ability to generate additional ethyl radicals into the gas phase. The results provide the experimental evidence for the concept of the catalysis sphere based on the radical-chain theory of the heterogeneous-homogeneous reactions of the catalytic pyrolysis of hydrocarbons.

Cite: Vasilʹeva N.A. , Ermolaev V.K. , Kuzʹmitskaya S.Y.
ESR Study of Radical Generation in the Course of Catalytic Pyrolysis of Hydrocarbons
Kinetics and Catalysis. 1999. V.40. N1. P.100-104. WOS Scopus РИНЦ ANCAN

Original: Васильева Н.А. , Ермолаев В.К. , Кузьмицкая С.Ю.
Исследование методом ЭПР генерации радикалов при каталитическом пиролизе углеводородов
Кинетика и катализ. 1999. Т.40. №1. С.111-115. РИНЦ publication_identifier_short.rz_viniti_identifier_type

Dates:

Submitted:	Apr 24, 1996
Published print:	Jan 1, 1999

Identifiers:

Web of science:	WOS:000078894900015
Scopus:	2-s2.0-0042994065
Elibrary:	13314278
Chemical Abstracts:	1999:176431
Chemical Abstracts (print):	130:281699

Citing:

DB	Citing
Web of science	5